Enantiomer Superpositions from Matter-Wave Interference of Chiral Molecules
نویسندگان
چکیده
Molecular matter-wave interferometry enables novel strategies for manipulating the internal mechanical motion of complex molecules. Here, we show how chiral molecules can be prepared in a quantum superposition two enantiomers by far-field diffraction and resulting tunnelling dynamics observed. We determine impact ro-vibrational phase averaging propose setup sensing enantiomer-dependent forces, parity-violating weak interactions, environment-induced superselection handedness, as suggested to resolve Hund's paradox. Using ab-initio calculations, identify [4]-helicene derivatives promising candidates implement proposal with state-of-the-art techniques. This work opens door metrology
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ژورنال
عنوان ژورنال: Physical Review X
سال: 2021
ISSN: ['2160-3308']
DOI: https://doi.org/10.1103/physrevx.11.031056